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Luperox® Crosslinking Peroxides

Description

Provides rubber and  polyolefins with outstanding mechanical, thermal and chemical performance, obtained through the formation of  bonds between the rubber chains.
This operation is called cross-linking or vulcanization.

 

A crosslink is a carbon-to-carbon bond between adjacent polymer chains.

 

 

 

 

 

 

Organic Peroxides are acting as free radical source.
Their thermal decomposition generates very active free radicals capable to abstract hydrogen atom from the polymer backbone. This is possible both in unsaturated and saturated polymer.
Two macroradicals can then recombine to create a direct C-C bond between adjacent polymer chains.

 

Innovation :

  • Scorch Protected
    Luperox® SP organic peroxide provides outstanding scorch protection and does not cause any loss of cross-linking density.
  • Controlled Speed Technology
    Luperox® CST organic peroxide combines efficient scorch protection and fast curing

 

Benefits

End Product :

 

  • Can be used for both unsaturated and saturated polymers
  • Superior heat and ageing stability
  • Excellent compression set, even at high temperature
  • Nitrosamine free
  • Easy to formulate
  • High compound shelf-life
  • Wide range of curing speed, high cross-linking density, and various physical forms obtainable.

 

Markets and Applications

 

Market

Polymer

 

 End product

Automotive

Elastomers

(EPDM, EPM,

HNBR,

NBR, FKM,...)

 

Belt, hoses, profiles,

O-rings, gaskets

Building / Construction

Elastomers

(EPDM, EPM,..)

EVA

PEX / XPLE

 

Profiles

Flooring and roofing

Pipes,

rotomolded containers

Cable

Elastomers

(EPDM, CPE,...)

EVA

XPLE

 

Insulation

and semi

conductor layers

Sport

EVA

 

Shoes soles

 

PBU

 

Golf ball cores

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

The main families of organic peroxides used for crosslinking rubber and plastics are :

  • Dialkyl peroxides, which are used, in either pure or extended forms, at higher temperatures (150-210°C), usually in conjunction with coagents
  • Perketals, which are used, in pure or extended forms, at lower temperatures (130-190oC) and are preferred when short cure cycle times are desired.

 

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Crosslinking
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